A tricarbonyl rhenium(I) complex with a pendant pyrrolidinium moiety as a robust and recyclable catalyst for chemical fixation of carbon dioxide in ionic liquid.

نویسندگان

  • Wing-Leung Wong
  • Kwong-Chak Cheung
  • Pak-Ho Chan
  • Zhong-Yuan Zhou
  • Kam-Han Lee
  • Kwok-Yin Wong
چکیده

A novel Re(I) complex covalently anchored with a pyrrolidinium moiety was successfully synthesized and used as an efficient and recyclable catalyst in the cycloaddition of CO2 with epoxides under mild reaction conditions to give excellent isolated yield and selectivity of cyclic carbonates in pyrrolidinium ionic liquid.

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عنوان ژورنال:
  • Chemical communications

دوره 21  شماره 

صفحات  -

تاریخ انتشار 2007